Effect of mixing enthalpy on relaxed and strained growth of III-(VyV1-yII)-V-I compound alloys using molecular-beam epitaxy.
 
Effect of mixing enthalpy on relaxed and strained growth of III-(VyV1-yII)-V-I compound alloys using molecular-beam epitaxy. 
 
Jan Genoe, József G. Németh, Bob Grietens, M. Behet, Roger Vounckx, Gustaaf Borghs
 
Abstract 

The strict virtual crystal model has been shown to describe accurately the mixing enthalpy of III-V ternary alloys. We allocate the different components of this model to both subreactions, i.e., the reactions forming III-V-I and III-V-II, present in the molecular-beam epitaxial growth of III-(VVII)-V-I compound alloys, and derive thereof a model that describes accurately the composition obtained. A good correspondence with experimental growth data is obtained. We apply this model to both relaxed and strained layer growth and the evolution in the composition is given when a relaxed layer is grown on a substrate with a different lattice constant.